Shujun Zhang

Why does relaxor-PT ferroelectric crystal have giant piezoelectricity? - The role of anisotropy and its applications

Perovskite ferroelectric materials are at the heart of electromechanical devices, such as medical imaging transducers, industrial nondestructive evaluation, and piezoelectric sensors, to name a few. Relaxor-PbTiO3 (relaxor-PT) ferroelectrics show superior dielectric/piezoelectric properties, far outperforming conventional ferroelectric Pb(ZrxTi1−x)O3 (PZT) ceramics. Why do relaxor-PT single crystals possess giant piezoelectricity? In the last 3 decades, different mechanisms have been proposed in attempts to comprehend its origin, thus benefiting the design of the next generation of ferroelectric materials. Analogous to PZT solid solution ferroelectrics, the morphotropic phase boundary (MPB) separating different ferroelectric phases possesses a flat free energy profile due to the similar free energies of the coexistent phases, which induces structural instability and promotes rotation of the polarization. Meanwhile, the good properties of relaxor-PT based materials are inherently associated with their unique local structural heterogeneity, i.e., the existence of nanoscale heterogeneous regions that coexist with normal ferroelectric domains, where the local energy competition will lead to a greatly flattened local energy profile, which is conducive to the polarization rotation. Both of the above can be categorized as forms of structural instability. In addition to the structural instability, unlike polycrystalline materials, the single crystals possess a strong anisotropic property, where the anisotropic free energy profile determines the easy paths for polarization change and corresponds to the enhanced properties. Depending on the phase and poling direction, the relaxor-PT ferroelectric crystals possess different engineered domain configurations, where the highest piezoelectric coefficient is not along the direction of spontaneous polarization but is contributed by the polarization rotation. All of these factors synergistically contribute to macroscopic dielectric and piezoelectric properties.

In this regard, the focus of this presentation is how to understand and take full advantage of the strong anisotropic feature of relaxor-PT ferroelectric crystals as well as exploring their multifunctional coupling phenomena for different applications. As expected, their properties, including piezoelectric and mechanical loss, are orientation dependent, so are based on the engineered domain configuration. Amazingly, the [011] poled rhombohedral relaxor-PT crystals possess many very unique features. Where a large in-plane strain under electric field exists, it opens up a new freedom to tailor numerous functionalities, while their distinct face-shear vibration mode gives these crystals potential for low frequency acoustic transducers and tactile sensors. Of particular interest is that the existing 71o domains in [011] poled rhombohedral crystal give identical projection of the indicatrix on the (011) and (100) planes, leading to a high transparency of the crystal, while the polarization rotation contributes to a superior electro-optic (EO) coefficient, offering great promise for miniaturization, portability, and ultralow driving voltage of EO devices. All these merits give us a good paradigm of how we can explore the new limits of relaxor-PT ferroelectric crystals in emerging applications, multifunctional coupling, and integration, with the hope that this will guide the design, fabrication, microstructure, properties, and applications of these ferroelectric crystals.

Presenter Bio

Shujun Zhang is a Professor of the Institute for Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Australia, prior to which, he was a senior scientist of the Materials Research Institute and Professor of the Materials Science and Engineering Department of Pennsylvania State University, USA. He has authored/co-authored over 500 technical papers (28,000 citations with H-index of 80 on Google Scholar) and holds 10 patents in the field of dielectric and piezoelectric materials. His research interests are focused on the fabrication-microstructure-property-application relationships of electronic materials for piezoelectric sensor, acoustic transducer, and energy storage/harvesting applications. Prof. Zhang has received a number of awards from various societies, including Fellow of the IEEE Ultrasonics, Ferroelectrics, and Frequency Control Society (UFFC-S, 2021); Fellow of the American Ceramic Society (2019); winner of the Ross Coffin Purdy Award at the American Ceramic Society (2020); the IEEE UFFC-S Ferroelectrics Young Investigator Award (2011) and Ferroelectrics Recognition Award (2021); ARC Future Fellow (2015-2019); Top researcher in the field of Ceramic Engineering in Australia (2021); and winner of one of the NSW Premier’s Prizes for Science & Engineering (2021). He is the TPC member for the IEEE International Ultrasonics Symposium (2014-) and the IEEE International Symposium on Applications of Ferroelectrics (ISAF 2016-), elected IEEE UFFC AdCom member (2016-2018) and VP for Ferroelectrics (2021-). He is the Associate Editor in Chief (EiC) for IEEE Transactions on UFFC, section EiC for Crystals, EiC for Microstructures, and Associate Editor for Science Bulletin and the Journal of the American Ceramic Society. He is the symposium organizer for the Electronic Materials & Applications Conference (ACerS, 2015-) and the general co-chair for the 2021 ISAF-ISIF-PFM conference in Sydney.

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